conversion of dagang vacuum residue into oxygen-containing organic compounds by photo-oxidation with h2o2 over tio2

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ID: 135571
2011
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Abstract
The photocatalytic depolymerization of Dagang vacuum residue (DVR) was carried out with H2O2 over TiO2 in a photochemical reactor. Most of the organic matter in DVR was converted into oxygen-containing organic compounds. The yields of carboxylic acids, oxalates, epoxy compounds, and hydroxyl compounds from DVR oxidation are 40.6%, 36.4%, 17.86%, and 13.5%, respectively. In addition, the oxidation causes significant decrease in viscosity and chromaticity of DVR. The related reaction mechanisms are discussed according to the experimental results.
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Authors ;Heng-Shen Xie;Zhi-Min Zong;Qing Wei;Tong Liu;Jian-Jun Zhao;Pei-Zhi Zhao;Shi-Hua Zhang;Xian-Yong Wei
Journal construction and building materials
Year 2011
DOI
10.1155/2011/869589
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