convergent synthesis of n,s-bis glycosylquinolin-2-ones via a pd-g3-xantphos precatalyst catalysis
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ID: 133022
2018
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Abstract
Buchwald-Hartwig-Migita cross-coupling of 1-thiosugars with α- or β-3-iodo-N-glycosylquinolin-2-ones has been accomplished under mild and operationally simple reaction conditions through the use of a Pd-G3 XantPhos palladacycle precatalyst. This new methodology has been successfully applied to a variety of α- or β-mono-, di-, and poly-thiosugar derivatives to efficiently synthesize a series of α- or β-N,S-bis-glycosyl quinolin-2-ones, which are difficult to synthesize by classical methods.
| Reference Key |
redjdal2018moleculesconvergent
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|---|---|
| Authors | ;Wafa Redjdal;Nada Ibrahim;Belkacem Benmerad;Mouad Alami;Samir Messaoudi |
| Journal | Journal of ethnopharmacology |
| Year | 2018 |
| DOI |
10.3390/molecules23030519
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| URL | |
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