kinetic investigation and dissolution behavior of cyanide alternative gold leaching reagents

Clicks: 236
ID: 132642
2019
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Abstract
Abstract Raising social awareness and environmental specifications on cyanide application force gold industry to search for alternative leaching reagents. Therefore, researchers worldwide investigate cyanide alternatives for gold recovery since several decades. Often the research activities cannot be compared directly, since different input materials and experimental conditions are used. Over the course of this study, different promising cyanide alternative reagents were investigated in terms of their capability of pure gold dissolution at different temperatures. All experiments took place under identical conditions by using uniform samples of 99.99% gold disks, to enable a comparability. Thiosulfate as one of the most promising reagent thiosulfate according to literature revealed an insufficient leaching behavior. The gold dissolution was hindered due to the formation of a sulfide passive layer. Also in the thiourea trials, a surface precipitation took place, though gold dissolution did not stop. The halogens iodine, bromine and the well-known gold solvent aqua regia dissolved gold very fast (up to ~1,000 mg·h−1·cm−2). Methanosulfonic acid (MSA) was not capable to extract any gold. The experiments were compared with cyanide trials at identical conditions. The average dissolution rate of investigated reagents at 25 °C shows following order: aqua regia > iodine > bromine > cyanide > thiourea > thiosulfate > MSA.
Reference Key
birich2019scientifickinetic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Alexander Birich;Srecko Stopic;Bernd Friedrich
Journal historia de la educación
Year 2019
DOI
10.1038/s41598-019-43383-4
URL
http://link.springer.com/article/10.1038/s41598-019-43383-4
Keywords
medicinescience

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