cyclopropanation of 5-(1-bromo-2-phenyl-vinyl)-3-methyl-4-nitro-isoxazoles under phase transfer catalysis (ptc) conditions
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ID: 128324
2015
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Abstract
Heavily substituted cyclopropane esters were prepared in high yields, complete diastereoselection and average (up to 58%) enantioselectivity. The reaction described herein entailed reacting 4-nitro-5-bromostyrylisoxazoles, a class of powerful Michael acceptors with malonate esters under the catalysis of 5 mol% of a chincona derived phase-transfer catalyst.
| Reference Key |
piras2015catalystscyclopropanation
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|---|---|
| Authors | ;Linda Piras;Maria Moccia;Mauro Cortigiani;Mauro F. A. Adamo |
| Journal | journal of essential oil research |
| Year | 2015 |
| DOI |
10.3390/catal5020595
|
| URL | |
| Keywords | Keywords not found |
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