cyclopropanation of 5-(1-bromo-2-phenyl-vinyl)-3-methyl-4-nitro-isoxazoles under phase transfer catalysis (ptc) conditions

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ID: 128324
2015
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Abstract
Heavily substituted cyclopropane esters were prepared in high yields, complete diastereoselection and average (up to 58%) enantioselectivity. The reaction described herein entailed reacting 4-nitro-5-bromostyrylisoxazoles, a class of powerful Michael acceptors with malonate esters under the catalysis of 5 mol% of a chincona derived phase-transfer catalyst.
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piras2015catalystscyclopropanation Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors
Journal journal of essential oil research
Year 2015
DOI
10.3390/catal5020595
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