Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photoreductants for Halogen Atom Abstraction Reactions

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2015
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Abstract
Luminescent Ce(III) complexes, Ce[N(SiMe3)2]3 (1) and [(Me3Si)2NC(RN)2]Ce[N(SiMe3)2]2 (R = (i)Pr, 1-(i)Pr; R = Cy, 1-Cy), with C(3v) and C(2v) solution symmetries display absorptive 4f → 5d electronic transitions in the visible region. Emission bands are observed at 553, 518, and 523 nm for 1, 1-(i) …
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Authors Yin H;Carroll PJ;Anna JM;Schelter EJ;;
Journal Journal of the American Chemical Society
Year 2015
DOI
DOI not found
URL
https://www.ncbi.nlm.nih.gov/pubmed/26151154
Keywords
National Center for Biotechnology Information NCBI NLM MEDLINE pubmed abstract nih national institutes of health national library of medicine haolin yin patrick j carroll eric j schelter pmid:26151154 doi:10.1021/jacs.5b05411

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