Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photoreductants for Halogen Atom Abstraction Reactions
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ID: 122015
2015
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Abstract
Luminescent Ce(III) complexes, Ce[N(SiMe3)2]3 (1) and [(Me3Si)2NC(RN)2]Ce[N(SiMe3)2]2 (R = (i)Pr, 1-(i)Pr; R = Cy, 1-Cy), with C(3v) and C(2v) solution symmetries display absorptive 4f → 5d electronic transitions in the visible region. Emission bands are observed at 553, 518, and 523 nm for 1, 1-(i) …
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h2015journalluminescent
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| Authors | Yin H;Carroll PJ;Anna JM;Schelter EJ;; |
| Journal | Journal of the American Chemical Society |
| Year | 2015 |
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