Colorless and Transparent Copolyimides and Their Nanocomposites: Thermo-Optical Properties, Morphologies, and Gas Permeabilities.
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ID: 114277
2019
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Abstract
A series of linear aromatic copolyimides (Co-PIs) were synthesized by reacting 4,4'-biphthalic anhydride (BPA) with various molar contents of 2,2'-bis(trifluoromethyl)benzidine (TFB) and p-xylylenediamine (p-XDA) in N,N'-dimethylacetamide (DMAc). Co-PI films were fabricated by solution casting and thermal imidization with poly(amic acid) (PAA) on glass plates. The thermo-optical properties and gas permeabilities of Co-PI films composed of various molar ratios of p-XDA (0.2⁻1.0 relative to BPA) were investigated. Thermal properties were observed to deteriorate with increasing p-XDA concentration. However, oxygen-transmission rates (O₂TRs) and optical transparencies improved with increasing p-XDA concentration. Co-PI hybrids with a 1:0.2:0.8 molar ratio of BPA:TFB:p-XDA and organically modified hectorite (STN) were prepared by the in situ intercalation method. The morphologies and the thermo-optical and gas permeation properties of the hybrids were examined as functions of STN loading (5⁻50 wt %). XRD and TEM revealed substantial increases in clay particle agglomeration in the Co-PI hybrid films as the clay loading was increased from 5 to 50 wt %. The coefficient of thermal expansion (CTE) and the O₂TR of a Co-PI hybrid film were observed to improve with increasing STN concentration; however, its optical transparency decreased gradually with increasing STN concentration.
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chang2019polymerscolorless
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| Authors | Hyeon Il Shin,Young-Je Kwark,Jin-Hae Chang;Hyeon Il Shin;Young-Je Kwark;Jin-Hae Chang; |
| Journal | Polymers |
| Year | 2019 |
| DOI |
10.3390/polym11040585
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