Synthesis of tetrakis bromine terminated phthalocyanine and its methyl methacrylate polymers via ATRP

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ID: 11218
2019
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Abstract
A phthalocyanine (Pc) initiator, tetrakis(2-bromopropyloxyester)ethylthiophthalocyaninatozinc(II) (ZnPc- Br), was prepared and successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) for the first time. Bromine end groups of the synthesized Pc took part in the initiation of the MMA chain growth. Polymerization was demonstrated by monomodal molecular weight distribution of the synthesized polymers and their increasing molecular weight behavior with reaction time. UV-Vis absorption, fluorescence, and transmittance properties of the polymers were also examined. The results indicate that the ZnPc-Br-based initiator is potentially applicable in ATRP applied to MMA in order to obtain and develop functional acrylic materials.
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canak2019synthesisturkish Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Tuba ÇAKIR ÇANAK;Damla YEŞİLDAĞ;Ilgın NAR;Esin HAMURYUDAN;İbrahim Ersin SERHATLI;
Journal turkish journal of chemistry
Year 2019
DOI
DOI not found
URL
http://dergipark.org.tr/download/article-file/739362
Keywords
phthalocyanine poly(methylmethacrylate) atom transfer radical polymerization Langmuir–Blodgett nanobiosensor nanolithography close-packed silica colloids porous film biodetection

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