New Horizons in Chemical Functionalization of Endohedral Metallofullerenes

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2020
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Abstract
This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are discussed, cage-opening reactions of EMFs are examined. Then, the selective bisfunctionalization of EMFs is explained. Finally, single-bonding derivatization of EMFs is addressed. The diversity and applicability of the chemical functionalization of endohedral metallofullerenes are presented to readers worldwide.
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Authors Michio Yamada;Michael T. H. Liu;Shigeru Nagase;Takeshi Akasaka;Yamada, Michio;Liu, Michael T. H.;Nagase, Shigeru;Akasaka, Takeshi;
Journal molecules
Year 2020
DOI
10.3390/molecules25163626
URL
https://doi.org/10.3390/molecules25163626
Keywords
Nanocarbon fullerene radicals electrochemistry addition reactions carbenes chemical functionalization endohedral metallofullerene lanthanide ions pericyclic reactions

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