Synthesis and Characterization of Polyacetylene with Side-chain Thiophene Functionality

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ID: 110543
2008
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Abstract
A new polyacetylene derivative with electroactive thiophene substituent, namely poly(2-methylbut-2-enyl thiophene-3-carboxylate) was synthesized and characterized. For this purpose, novel acetylene monomer was synthesized by the reaction of 3- thiophenecarboxylic acid with propargyl bromide and polymerized with a Rh catalyst to give the corresponding polymer. The chemical structure of the polymer was characterized to comprise the conjugated backbone and electroactive thiophene side group. UV spectral changes of the polymer with temperature were also studied. The polymer exhibited better thermal stability than the unsubstituted polyacetylenes.
Reference Key
koz2008internationalsynthesis Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Banu Koz;Baris Kiskan;Yusuf Yagci;Koz, Banu;Kiskan, Baris;Yagci, Yusuf;
Journal International journal of molecular sciences
Year 2008
DOI
10.3390/ijms9030383
URL
https://www.mdpi.com/1422-0067/9/3/383/htm
Keywords
conjugated polymer polyacetylene helical polymer thiophene.

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