A Novel Dimer of ?-Tocopherol
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ID: 10984
2008
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Abstract
Decomposition of the complex 4, formed between the ?-tocopherol ortho-quinone methide (2) and NMMO, by fast heating from −78∘C to 70∘C in inert solvents produces a novel ?-tocopherol dimer with 6?,12?-dibenzo[b,f][1,5]dioxocine structure (5) which—in contrast to the well-known spiro-dimer of ?-tocopherol (3)—is symmetrical. This is the first example of a direct reaction of the highly transient zwitterionic, aromatic precursor 2a in the formation of the ortho-quino
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| Reference Key |
anjan2008aorganic
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|---|---|
| Authors | Patel, Anjan;Mazzini, Francesco;Netscher, Thomas;Rosenau, Thomas;Patel, Anjan;Mazzini, Francesco;Netscher, Thomas;Rosenau, Thomas; |
| Journal | organic chemistry international |
| Year | 2008 |
| DOI |
10.1155/2008/742590
|
| URL | |
| Keywords | Keywords not found |
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