Photochromism of Dihydroindolizines Part XI: Synthesis of Novel Carbon-Rich Photochromic Dihydroindolizines-Based Potential Electronic Devices
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ID: 10980
2008
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Abstract
Novel carbon-rich photochromic dihydroindolizine (DHI) derivatives substituted in the fluorene part (region A) in addition to the new spirocyclopropene 6 have been synthesized. The synthesis of dimethyl 2,7-diethynylspiro[cycloprop[2]ene-1,9-fluorene]-2,3-dicarboxylate precursor 6 was accomplished in five steps, starting with the literature known conversion of fluorene to 2,7-dibromo-9H-fluoren-9-one in 56% yield over three steps. The chemical structures of the new synthesized materials have been elucidated by both analytical and spectroscopic tools. Three alterative synthetic pathways for the synthesis of D
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| Reference Key |
abdelmgeed2008photochromismorganic
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|---|---|
| Authors | Ahmed, Saleh Abdel-Mgeed;Ahmed, Saleh Abdel-Mgeed; |
| Journal | organic chemistry international |
| Year | 2008 |
| DOI |
10.1155/2008/959372
|
| URL | |
| Keywords | Keywords not found |
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