SYNTHESIS OF CYCLEN BODIPY DYAD AND ITS METAL COMPLEXES: EVALUATION OF ANION RECOGNITION FEATURES

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ID: 10927
2019
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Abstract
In this study, a new compound, viz. 4,4-Difluoro-8-(1,4,7,10-tetraazacyclododecane)methyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene ( 1 ), and its metal complexes ( 1-Zn , 1-Cu , and  1-Ni ) are synthesized and spectroscopically characterized (UV-Vis, luminescence-fluorescence, NMR, FTIR, and MS). Anion sensing properties of compound  1 and its metal complexes ( 1-Zn , 1-Ni  and 1-Cu ) are tested in the presence of various anionic species in acetonitrile media. Fluorescence measurements indicated that,  1-Ni  and 1-Cu  do not have any selectivity towards various anions except weak interactions. On the other hand 1-Zn shows good response and selectivity toward acetate ion based on fluorescence enhancement. In addition, JOB studies demonstrate that  the interaction between  1-Zn and acetate ion were with a ratio of 1:2 and limit of detection (LOD) of  1-Zn was calculated as 4.76x10 -6 M for acetate ion detection. Moreover,  1-Zn provides a certain change in color in the presence of acetate. The results demonstrate that  1-Zn can be utilized for fluorogenic and naked eye detection of acetate anion.
Reference Key
algi2019synthesismugla Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Fatih Algı;Serkan Karakaya;
Journal mugla journal of science and technology
Year 2019
DOI
10.22531/muglajsci.512383
URL
http://dergipark.org.tr/download/article-file/722739
Keywords
BODIPY Cyclen Acetate Ion Zinc(II)

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