INVESTIGATION OF PYRIDINE-CATALYZED HUISGEN CYCLOADDITION REACTIONS IN NICOTINE-BASED TASK SPPECIFIC IONIC LIQUID
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ID: 10833
2012
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Abstract
Nicotine-based ionic liquid has been prepared and used as a green, alternative recyclable solvent as well as catalyst for pyridine-catalyzed Huisgen reaction. It involves pyridine promoted addition of dimethylacetylenedicarboxylate to aldehydes or N-tosylimines leading to efficient synthesis of 2-benzoylfumarates and 1-azadienes respectively. The same reactions repeated under pyridine free odorless ionic liquid conditions. The improved results were obtained in terms of enhanced yields, with minimal work up.
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hullio2012investigationjournal
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| Authors | AHMED ALI HULLIO;AHMED ALI HULLIO;G.M MASTOI;G.M MASTOI; |
| Journal | journal of ongoing chemical research |
| Year | 2012 |
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| Keywords | Keywords not found |
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