Temperature expansions in the square-shoulder fluid. II. Thermodynamics.
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ID: 103089
2020
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Abstract
In Paper I [O. Coquand and M. Sperl, J. Chem. Phys. 152, 124112 (2020)], we derived analytical expressions for the structure factor of the square-shoulder potential in a perturbative way around the high- and low-temperature regimes. Here, various physical properties of these solutions are derived. In particular, we investigate the large wave number sector and relate it to the contact values of the pair-correlation function. Then, the thermoelastic properties of the square-shoulder fluids are discussed.
| Reference Key |
coquand2020temperaturethe
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| Authors | Coquand, O;Sperl, M; |
| Journal | The Journal of Chemical Physics |
| Year | 2020 |
| DOI |
10.1063/1.5142662
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