Direct Synthesis of Methyl Formate from CO With Phosphine-Based Polymer-Bound Ru Catalysts.

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ID: 102399
2019
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Abstract
Methyl formate was produced in one pot through the hydrogenation of CO to formic acid/formate followed by an esterification step. The route offers the possibility to integrate renewable energy into the fossil-based chemical value chain. In this work, a phosphine-polymer-anchored Ru complex was shown to be an efficient solid catalyst for the direct hydrogenation of CO to methyl formate. The 1,2-bis(diphenylphosphino)ethane-like polymer presented the highest activity with a turnover number (TON) of up to 3401 at 160 °C. The reaction parameters were systemically investigated to optimize the reaction towards the formation of methyl formate. This catalyst could be reused seven times without a significant decrease in activity. Evolution of the catalytic Ru center during the reaction was revealed, and a possible reaction mechanism was proposed.
Reference Key
sun2019directchemsuschem Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Sun, Ruiyan;Kann, Anna;Hartmann, Heinrich;Besmehn, Astrid;Hausoul, Peter J C;Palkovits, Regina;
Journal ChemSusChem
Year 2019
DOI
10.1002/cssc.201900808
URL
Keywords
heterogeneous catalysis ruthenium co2 hydrogenation methyl formate phosphine polymer

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