Molecularly Imprinted Polymers: Thermodynamic and Kinetic Considerations on the Specific Sorption and Molecular Recognition

Clicks: 208
ID: 101356
2008
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Abstract
This article presents a work aiming at thermodynamically and kinetically interpreting the specific sorption and recognition by a molecularly imprinted polymer. Using Boc-L-Phe-OH as a template, the imprinted material was prepared. The result indicates that the prepared polymer can well discriminate the imprint species from its analogue (Boc-D-Phe-OH), so as to adsorb more for the former but less for the latter. Kinetic analysis indicates that this specific sorption, in nature, can be a result of a preferential promotion. The imprint within the polymer causes a larger adsorption rate for the template than for the analogue. Thermodynamic study also implies that the molecular induction from the specific imprint to the template is larger than to the analogue, which thus makes the polymer capable of preferentially alluring the template to bind.
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tong2008molecularlysensors Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Tong, Kejun;Li, Wuke;Zheng, Mingxia;Huang, Xing;Li, Songjun;
Journal sensors
Year 2008
DOI
DOI not found
URL
http://www.mdpi.com/1424-8220/8/4/2854/
Keywords
Biology (General) Medicine Chemical technology Technology Descriptive and experimental mechanics Science physical and theoretical chemistry chemical engineering neurosciences. biological psychiatry. neuropsychiatry social sciences (general) water supply for domestic and industrial purposes hydraulic engineering thermodynamics

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