crystal structure of dimethylformamidium bis(trifluoromethanesulfonyl)amide: an ionic liquid
Clicks: 115
ID: 238999
2016
At 100 K, the title molecular salt, C3H8NO+·C2F6NO4S2−, has orthorhombic (P212121) symmetry; the amino H atom of bis(trifluoromethanesulfonyl)amine (HNTf2) was transferred to the basic O atom of dimethylformamide (DMF) when the ionic liquid components were mixed. The structure displays an O—H...N hydrogen bond, which links the cation to the anion, which is reinforced by a non-conventional C—H...O interaction, generating an R22(7) loop. A further very weak C—H...O interaction generates an [001] chain.
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cardenas2016actacrystal
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| Authors | ;Allan Jay P. Cardenas;Molly O'Hagan |
| Journal | Disability and rehabilitation |
| Year | 2016 |
| DOI | 10.1107/S2056989016012251 |
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