polyvinylpyrrolidone-bromine complex: an efficient polymeric reagent for selective preparation of benzyl bromides in the presence of hexamethyldisilane

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ID: 155635
2012
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Abstract
Benzylic bromides were conveniently obtained in high yields via the reaction of the corresponding alcohols with crosslinked polyvinylpyrrolidone-bromine complex (PVPP-Br2)/hexamethyldisilane in chloroform at reflux condition. Selective conversion of benzyl alcohol to benzyl bromide in the presence of primary aliphatic alcohols, e.g. 2-phenylethanol was also achieved.DOI: http://dx.doi.org/10.4314/bcse.v26i2.14
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Authors ;Moslem M. Lakouraj;Masoud Mokhtary
Journal Experimental physiology
Year 2012
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