Reaction of ketone hydrazones with TeCl: isolation and reactions of novel divinyl telluride.
Clicks: 218
ID: 108598
2020
The reaction of acetophenone hydrazones with TeCl4 in the presence of DBU gave a mixture of divinyl ditellurides and divinyl tellurides, which easily reacted with Cu powder in refluxing toluene to afford divinyl tellurides in good yields. The reaction of divinyl tellurides with bromine (1.2 eq.) gave the corresponding tellurium dibromide rather than the addition of the double bond whereas 3 molar amount of bromine gave excess brominated and oxidized products. The reaction of divinyl tellurides with 2-(trimethylsilyl)phenyl triflate in the presence of CsF gave (E)-2-alkenyldiaryl tellurides in good yields.
| Reference Key |
okuma2020reactionorganic
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | Okuma, Kentaro;Qu, Yuxuan;Suetome, Aoi;Nagahora, Noriyoshi; |
| Journal | Organic & biomolecular chemistry |
| Year | 2020 |
| DOI | 10.1039/d0ob00782j |
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.