Controlling gas selectivity in molecular porous liquids by tuning the cage window size.
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2020
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Abstract
Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH4-selective, which is understood using 129Xe, 1H, and pulsed-field gradient NMR spectroscopy.| Reference Key |
egleston2020controllingangewandte
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| Authors | Egleston, Benjamin;Luzyanin, Konstantin;Brand, Michael;Clowes, Rob;Briggs, Michael;Greenaway, Rebecca L;Cooper, Andrew; |
| Journal | angewandte chemie (international ed in english) |
| Year | 2020 |
| DOI | 10.1002/anie.201914037 |
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