Heteroannulation enabled by a bimetallic Rh(iii)/Ag(i) relay catalysis: application in the total synthesis of aristolactam BII.
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2017
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Abstract
A redox-neutral bimetallic Rh(iii)/Ag(i) relay catalysis allowed the efficient construction of 3-alkylidene isoindolinones and 3-alkylidene isobenzofuranones. The Rh(iii) catalyst was responsible for the C-H monofluoroalkenylation reaction, whereas the Ag(i) salt was an activator for the follow-up cyclization. The methodology developed was applied as a key step in the rapid total synthesis of the natural product aristolactam BII.| Reference Key |
ji2017heteroannulationchemical
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| Authors | Ji, Wei-Wei;Lin, E;Li, Qingjiang;Wang, Honggen; |
| Journal | Chemical communications (Cambridge, England) |
| Year | 2017 |
| DOI | 10.1039/c7cc02105d |
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