Calix[4]resorcinarene-based [Co] coordination cages mediated by isomorphous auxiliary ligands for enhanced proton conduction.

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ID: 76715
2019
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Abstract
We herein propose a design assembly of calix[4]resorcinarene-based proton-conductive [Co16] coordination cages (1-SO3H and 1-OH) by carefully mediating the acidic sites of isomorphous auxiliary ligands. Markedly, 1-SO3H exhibits a proton conductivity that increased about 1 order of magnitude relative to its counterpart 1-OH, reaching 1.35 Ɨ 10-2 S cm-1 at 90 Ā°C and under 98% relative humidity.
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guo2019calix4resorcinarenebasedchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Guo, Ting-Ting;Cheng, Dong-Ming;Yang, Jin;Xu, Xianxiu;Ma, Jian-Fang;
Journal Chemical communications (Cambridge, England)
Year 2019
DOI 10.1039/c9cc01828j
URL
Keywords
Raman Spectroscopy supramolecular self-assembly halogen bonding resorcinarene reversible addition fragmentation chain transfer polymerization

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