MoS coated CoS nanocomposites as counter electrodes in Pt-free dye-sensitized solar cells.

Expensive Pt counter electrodes remain an obstacle for the commercialization of dye-sensitized solar cells (DSSCs). Therefore, research focusing on low-cost alternative counter electrode materials has been considered important for their commercialization. Here, the fabrication of dye-sensitized solar cells has been performed utilizing CoS and MoS coated CoS nanocomposite materials as the counter electrode, which are synthesized via a hydrothermal route involving low-cost precursor materials. The experimental results obtained from XRD, XPS, EDX, SEM, TEM, and Raman etc. have confirmed the successful formation of CoS and MoS coated CoS nanocomposites. The electrochemical characterization of these materials is performed, which suggests that the electrocatalytic activity towards the liquid iodine electrolyte of these materials is as good as that of the conventional Pt counter electrodes. So, dye-sensitized solar cell devices are fabricated by interpolating a (cis-bis(isothiocyanato)bis(2,2'-bipyridyl-4,4'-dicarboxylato)ruthenium(ii)) dye-loaded TiO photoanode and CoS, MoS coated CoS and Pt counter electrodes using iodine/iodide as a liquid electrolyte. The devices fabricated with CoS counter electrodes have shown an open circuit voltage of 790 mV, a short circuit current of 11.9 mA cm, a fill factor of 0.54, and a power conversion efficiency of 6%. On the other hand, the device based on a Pt counter electrode has shown an open circuit voltage of 773 mV, a short circuit current of 13.4 mA cm, a fill factor of 0.54, and a power conversion efficiency of 6.6%. In addition, MoS coated with a CoS counter electrode has shown the best performance with an open circuit voltage of 763 mV, a short circuit current of 20.1 mA cm, a fill factor of 0.42, and a power conversion efficiency of 7.6%.