Stereoselective olefin cyclopropanation under aerobic conditions with an artificial enzyme incorporating an iron-chlorin e6 cofactor
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2017
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Myoglobin has recently emerged as a promising biocatalyst for catalyzing carbene-mediated cyclopropanation, a synthetically valuable transformation not found in nature. Having naturally evolved for binding dioxygen, the carbene transferase activity of ...
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| Authors | Gopeekrishnan Sreenilayam, Eric J. Moore, Viktoria Steck, Rudi Fasan;Gopeekrishnan Sreenilayam;Eric J. Moore;Viktoria Steck;Rudi Fasan; |
| Journal | ACS catalysis |
| Year | 2017 |
| DOI | 10.1021/acscatal.7b02583 |
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