Intermolecular carbene SâH insertion catalysed by engineered myoglobin-based catalysts
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2015
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Abstract
The first example of a biocatalytic strategy for the synthesis of thioethers via an intermolecular carbene SâH insertion reaction is reported. Engineered variants of sperm whale myoglobin were found to efficiently catalyze this CâS bond forming transformation across a diverse set of aryl and alkyl mercaptan| Reference Key |
tyagi2015chemicalintermolecular
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| Authors | Vikas Tyagi;Vikas Tyagi;Rachel B. Bonn;Rachel B. Bonn;Rudi Fasan;Rudi Fasan; |
| Journal | Chemical science |
| Year | 2015 |
| DOI | 10.1039/C5SC00080G |
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