anion effect of zinc source on chemically deposited zns(o,oh) films

The study on the anion effect of different Zn sources—Zn(CH3COO)2, ZnCl2, ZnI2, Zn(NO3)2 and ZnSO4—on the chemical deposition of ZnS(O,OH) films revealed that the growth rate and composition of the ZnS(O,OH) layer depend on the instability constant (pK) value of the corresponding Zn-complex Zn(L)n in the chemical bath solution. In the region of pKZn(NH3)2+>pKZn(L)n the ZnS(O,OH) film's growth rate and ZnS concentration in films increased with the increasing pK value of the used Zn salt complex up to the pK value of the Zn[NH3]2+ complex and decreased in the region where pKZn(NH3)2+

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Authors	;K. Ernits;K. Muska;M. Danilson;J. Raudoja;T. Varema;O. Volobujeva;M. Altosaar
Journal	bulletin of the korean chemical society
Year	2009
DOI	10.1155/2009/372708
URL	http://dx.doi.org/10.1155/2009/372708 https://doi.org/10.1155/2009/372708
Keywords	materials of engineering and construction mechanics of materials