A Novel Dimer of ?-Tocopherol

Clicks: 135
ID: 10984
2008
Decomposition of the complex 4, formed between the ?-tocopherol ortho-quinone methide (2) and NMMO, by fast heating from −78∘C to 70∘C in inert solvents produces a novel ?-tocopherol dimer with 6?,12?-dibenzo[b,f][1,5]dioxocine structure (5) which—in contrast to the well-known spiro-dimer of ?-tocopherol (3)—is symmetrical. This is the first example of a direct reaction of the highly transient zwitterionic, aromatic precursor 2a in the formation of the ortho-quino
Reference Key
anjan2008aorganic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Patel, Anjan;Mazzini, Francesco;Netscher, Thomas;Rosenau, Thomas;Patel, Anjan;Mazzini, Francesco;Netscher, Thomas;Rosenau, Thomas;
Journal organic chemistry international
Year 2008
DOI 10.1155/2008/742590
URL
Keywords Keywords not found

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

No comments yet. Be the first to comment on this article.